Determination of Benzo[b]naphtho[2,3-d]thiophene (BNT) in Sediments using Selective Heavy Atom Induced Room-Temperature Phosphorimetry

نویسندگان

  • Carlos Eduardo Cardoso
  • Ricardo Q. Aucélio
چکیده

As características fosforescentes do benzo[b]nafto[2,3-d]tiofeno (BNT) foram estudadas sob diferentes condições experimentais. Melhores resultados foram obtidos utilizando-se Tl(I) e Pb(II) como indutores de fosforescência, em ambos os casos usando dodecilsulfato de sódio (SDS) como modificador de superfície. Nestas duas condições, curvas analíticas de 3 ordens de magnitude forneceram limites de detecção e quantificação de respectivamente 0,6 e 2,0 ng na presença de Tl(I) e 3,2 e 10,7 ng na presença de Pb(II). A potencialidade da metodologia desenvolvida para determinação de BNT em nível de traços foi testada usando amostras de sedimento enriquecidas com o analito de interesse e Pb(II) como átomo pesado seletivo para indução de fosforescência. A recuperação de BNT foi bastante satisfatória (101,5±7,4%, n=6) indicando que o método pode ser aplicado para a análise de amostras complexas. A interferência de outros hidrocarbonetos policíclicos aromáticos (pireno, criseno, carbazol, 7,9dimetilbenzo[c]acridina e dibenzotiofeno) foi avaliada e o método foi considerado seletivo na presença destas substâncias.

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تاریخ انتشار 2006